Boron trifluoride etherate → HCID 10754935, compound

HRID 366377Notes

Reaction equation

HRID 366377 reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]#[N:9].[CH3:10][O:11][C:12]1[CH:21]=[CH:20][CH:19]=[C:18]2[C:13]=1[CH2:14][CH2:15][CH2:16][C:17]2=O.B(F)(F)F.CCOCC>>[NH2:9][C:8]1[C:16]2[CH2:15][CH2:14][C:13]3[C:12]([O:11][CH3:10])=[CH:21][CH:20]=[CH:19][C:18]=3[C:17]=2[N:1]=[C:2]2[C:3]=1[CH:4]=[CH:5][CH:6]=[CH:7]2

Participants

4

Reactant 3

HCID 8000Boron trifluoride etherateHCID 366205-MethoxytetraloneHCID 729132-Aminobenzonitrile

Product 1

HCID 10754935HCID 10754935, compound

Procedure

2-amino-1-cyano-benzene (5.0 g, 42.3 mmol), 3, 4-dihydro-5-methoxy-[2H)-napthalen-1-one) (Aldrich Chemicals) (8.1 g, 46.0 mmol) and boron trifluoride diethyl etherate (1M, 5.7 ml, 46.6 mmol) were treated according to general procedure described herein to give the title compound.

Sources & evidence

ORD record
ord-f024560e82df4e3cb9b57450e961dbc5
Source dataset
uspto-grants-2000_10
Patent number
US06130228

Reaction notes

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