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HRID366503

反应详情

EQUATION

反应方程式

HRID 366503 的结构方程式

REACTANTS

反应物

2
结构：C[Si](C)(C)CCS(=O)(=O)n1cc(C2CCN(C(=O)OCc3ccccc3)CC2)c2cc(C#N)ccc21
HCID22615554

未命名化合物

结构：CC(C)(C)OC(=O)N1CCC(c2c[nH]c3ccc(F)cc23)CC1
HCID22714417

未命名化合物

PRODUCTS

生成物

1
结构：C[Si](C)(C)CCS(=O)(=O)n1cc(C2CCNCC2)c2cc(C#N)ccc21
HCID22615721

未命名化合物

PROCEDURE

实验过程

Proceeding as described in Example 19, Step 3, but substituting 1-benzyloxycarbonyl-4-(5-cyano-1-methanesulfonylindol-3-yl)piperidine with 1-benzyloxycarbonyl-4-[5-cyano-1-(2-trimethylsilylethanesulfonyl)indol-3-yl]piperidine (prepared as described in Example 14, Step 2, by substituting 1-benzyloxycarbonyl-4-(5-cyanoindol-3-yl)piperidine for N-tert-butoxycarbonyl-4-(5-fluoroindol-3-yl)piperidine] gave 4-[5-cyano-1-(2-trimethylsilyl-ethanesulfonyl)indol-3-yl]piperidine.

WORKUP

后处理

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