Hexanal → HCID 54015306, compound

Participants

Reaction Steps

A 38-mL stainless steel autoclave was charged with 1.40 g (10.0 mmol.) of 2-amino-4-methyl-6-methoxy-1,3,5-triazine, 204 mg of 5-% Pd-carried active carbon, 2.00 g (20.0 mmol.) of 1-hexanal and 15 mL of 1-hexanol. After the inside of the system was fully purged with a nitrogen gas, the reaction was conducted at a reaction temperature of 200° C. for twenty hours and under a hydrogen gas (initial pressure of 50 kg/cm2). After the completion of the reaction, unreacted starting materials were determined. As a result, the conversion ratio of the starting materials was 88.0%. As a result that the reaction product were analyzed, 2-n-hexylamino-4-methyl-6-methoxy-1,3,5-triazine was obtained at a yield of 67.0%.

Provenance & Evidence