HCID 54332191, compound → Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-, ether with 2-(hydroxymethyl)-2-methyl-1,3-propanediol (3:1)

HRID 36828Notes

Reaction equation

HRID 36828 reaction equation
C([O:8][CH2:9][CH2:10][O:11][CH2:12][C:13]([CH2:27][O:28][CH2:29][CH2:30][O:31]CC1C=CC=CC=1)([CH2:15][O:16][CH2:17][CH2:18][O:19]CC1C=CC=CC=1)[CH3:14])C1C=CC=CC=1>CO.[OH-].[OH-].[Pd+2].[Pd]>[OH:31][CH2:30][CH2:29][O:28][CH2:27][C:13]([CH2:12][O:11][CH2:10][CH2:9][OH:8])([CH2:15][O:16][CH2:17][CH2:18][OH:19])[CH3:14]

Participants

5

Reactant 1

HCID 54332191HCID 54332191, compound

Product 1

HCID 22328182Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-, ether with 2-(hydroxymethyl)-2-methyl-1,3-propanediol (3:1)Yield 99%

Reagents, catalysts & solvents 3

HCID 23938PalladiumCatalystHCID 9942167Palladium hydroxideCatalystHCID 887MethanolSolvent

Procedure

A mixture of 1,1,1-tris(benzyloxyethoxymethyl)ethane (13.9 g, 0.027 mol) and palladium hydroxide on carbon, Pd content 20% (2.8 g) in 100 mL of methanol was hydrogenated at 50 psi in a Parr apparatus for 4 hrs. The catalyst was removed by filtration through Celite and the filtrate was evaporated under reduced pressure to give 1,1,1-tris(hydroxyethoxymethyl)ethane (6.7 g, 0.026 mol, 99%).

Workup

  1. customThe catalyst was removed by filtration through Celite
  2. customthe filtrate was evaporated under reduced pressure

Sources & evidence

ORD record
ord-49db3078c15546478773e110eb611ace
Source dataset
uspto-grants-1995_05
Patent number
US05417959

Reaction notes

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