Hydrazoic acid → HCID 178427292, compound

HRID 370528Notes

Reaction equation

HRID 370528 reaction equation
[C:1]1([CH3:12])[CH:6]=[CH:5][C:4]([S:7]([C:10]#[N:11])(=[O:9])=[O:8])=[CH:3][CH:2]=1.[NH:13]=[N+:14]=[N-:15]>C1C=CC=CC=1>[C:1]1([CH3:12])[CH:2]=[CH:3][C:4]([S:7]([C:10]2[NH:15][N:14]=[N:13][N:11]=2)(=[O:8])=[O:9])=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 24530Hydrazoic acidHCID 87946p-Toluenesulphonyl cyanide

Product 1

HCID 178427292HCID 178427292, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

A mixture of p-toluenesulfonyl cyanide (0.0 g.) and excess hydrazoic acid in 50 ml. of benzene is stirred at room temperature for 20 hours. The product is filtered off, dissolved in ether, filtered through celite and evaporated to a solid which on trituration with benzene has a melting point, 133°-135° C.

Workup

  1. filtrationThe product is filtered off
  2. dissolutiondissolved in ether
  3. filtrationfiltered through celite
  4. customevaporated to a solid which on trituration with benzene
  5. customa melting point, 133°-135° C.

Sources & evidence

ORD record
ord-9131042ccf094d209fbcef9bf702c87c
Source dataset
uspto-grants-1985_07
Patent number
US04526978

Reaction notes

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