Toluene → HCID 86739467, compound

HRID 371190Notes

Reaction equation

HRID 371190 reaction equation
C1(C)C=CC=CC=1.C(Cl)Cl.[C:11]1(=[O:17])[NH:15][C:14](=[O:16])[CH2:13][CH2:12]1.[Cl:18]([O-:22])(=[O:21])(=[O:20])=[O:19].[Li+:23]>O.CCOCC>[C:14]1(=[O:16])[NH:15][C:11](=[O:17])[CH2:12][CH2:13]1.[Cl:18]([O-:22])(=[O:21])(=[O:20])=[O:19].[Li+:23]

Participants

7

Reactant 4

HCID 1140TolueneHCID 6344DichloromethaneHCID 11439SuccinimideHCID 23665649Lithium perchlorate

Product 1

HCID 86739467HCID 86739467, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 3283Diethyl EtherSolvent

Procedure

To a solution containing 420 ml toluene, 195 ml methylene chloride, 75 ml ether and 5.15 g of succinimide is added 2.0 ml of water and 18.5 g of lithium perchlorate. The mixture is stirred for 18 hrs. The solids are removed by filtration, washed 2 times with 50 ml of cold 4:1, hexane:methylene chloride, and dried `in vacuo` to give 24.18 g of succinimide/lithium perchlorate complex.

Workup

  1. customThe solids are removed by filtration
  2. washwashed 2 times with 50 ml of cold 4:1, hexane
  3. dry with materialmethylene chloride, and dried `in vacuo`
  4. customto give 24.18 g of succinimide/lithium perchlorate complex

Sources & evidence

ORD record
ord-9859382516764bde81a81a56ba7ad5cc
Source dataset
uspto-grants-1985_07
Patent number
US04529811

Reaction notes

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