Ethanol → HCID 23665997, compound

HRID 371373Notes

Reaction equation

HRID 371373 reaction equation
[CH2:1](Br)[CH:2]=[CH2:3].[S:5]([O-:9])([O-:8])(=[O:7])=[S:6].[Na+:10].[Na+].C(O)C>O>[CH2:1]([O:8][S:5]([O-:9])(=[O:7])=[S:6])[CH:2]=[CH2:3].[Na+:10]

Participants

5

Reactant 3

HCID 702EthanolHCID 7841Allyl bromideHCID 24477Sodium Thiosulfate

Product 1

HCID 23665997HCID 23665997, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of allyl bromide (100 g), sodium thiosulphate (212.5 g), ethanol (90 ml) and water (40 ml) was stirred and heated to reflux for 15 minutes, giving a homogeneous solution. The solution was allowed to cool somewhat, and ethanol and water were then evaporated under vacuum. The solid residue was added to absolute ethanol, and the solvent was then evaporated under vacuum to remove more water. The residue was stirred with hot ethanol (800 ml), and the suspension thus obtained was filtered. On cooling, the filtrate deposited a white solid (109.2 g). The NMR spectrum of the sold showed that it consisted of 80% by weight of sodium allylthiosulphate, 11% by weight of water and 9% by weight of inorganic salt.

Workup

  1. temperatureheated
  2. temperatureto reflux for 15 minutes
  3. customgiving a homogeneous solution
  4. temperatureto cool somewhat
  5. customethanol and water were then evaporated under vacuum
  6. additionThe solid residue was added to absolute ethanol
  7. customthe solvent was then evaporated under vacuum
  8. customto remove more water
  9. stirringThe residue was stirred with hot ethanol (800 ml)
  10. customthe suspension thus obtained
  11. filtrationwas filtered
  12. temperatureOn cooling

Sources & evidence

ORD record
ord-d0fc953078734f21bd6184a6133581ab
Source dataset
uspto-grants-1985_07
Patent number
US04532080

Reaction notes

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