m-Chloroperbenzoic acid → 2-Bromo-5-phenylsulfinylpyridine

HRID 372739Notes

Reaction equation

HRID 372739 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[CH:4][N:3]=1.ClC1C=CC=C(C(OO)=[O:23])C=1>>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[O:23])=[CH:4][N:3]=1

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 151690012-Bromo-5-(phenylthio) pyridine

Product 1

HCID 203265642-Bromo-5-phenylsulfinylpyridine

Procedure

Following the procedure of Example 7 2-bromo-5phenylthiopyridine is converted to 2-bromo-5-(phenylsulfinlyl) pyridine with m-chloroperbenzoic acid.

Sources & evidence

ORD record
ord-067394e0ce22491e9266f61e69cf67eb
Source dataset
uspto-grants-1978_05
Patent number
US04092321

Reaction notes

Loading…