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HRID373130

反应详情

EQUATION

反应方程式

HRID 373130 的结构方程式

REACTANTS

反应物

2
结构：[CH3][Sn]([CH3])([CH3])[N]=[N+]=[N-]
HCID5104973

Azidotrimethyltin(IV)

C3H9N3Sn

结构：CCCCc1nc2ccc(C)cc2c(=O)n1Cc1ccc(-c2cccnc2C#N)cc1
HCID19811513

未命名化合物

PRODUCTS

生成物

1
结构：CCCCc1nc2ccc(C)cc2c(=O)n1Cc1ccc(-c2cccnc2-c2nnn[nH]2)cc1
HCID178441453

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

A solution of the product of step C (1.0 eq.) is added trimethylstannylazide (3 eq.) in toluene (3 mL) and heated to reflux for 36 h. The mixture is cooled to rt, concentrated and then can be purified by flash chromatography on SiO2 to give the titled compound.

WORKUP

后处理

  1. temperatureheated
  2. temperatureto reflux for 36 h
  3. concentrationconcentrated
  4. customcan be purified by flash chromatography on SiO2