Chlorine → HCID 53829400, compound

HRID 374858Notes

Reaction equation

HRID 374858 reaction equation
[N+:1]([C:4]1[CH:10]=[C:9]([S:11]([C:14]([F:17])([F:16])[F:15])(=[O:13])=[O:12])[CH:8]=[CH:7][C:5]=1[NH2:6])([O-:3])=[O:2].[Cl:18]Cl>C(O)(=O)C>[N+:1]([C:4]1[CH:10]=[C:9]([S:11]([C:14]([F:17])([F:15])[F:16])(=[O:13])=[O:12])[CH:8]=[C:7]([Cl:18])[C:5]=1[NH2:6])([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 24526ChlorineHCID 45294692-Nitro-4-(trifluoromethanesulfonyl)aniline

Product 1

HCID 53829400HCID 53829400, compoundYield 95.3%

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

27 g of 2-nitro-4-trifluoromethylsulphonyl-aniline were chlorinated with 10 g of chlorine in 100 ml of acetic acid analogously to Example 14. 29 g of 2-nitro-4-trifluoromethylsulphonyl-6-chloro-aniline were obtained, melting point: 138°-39° C.

Sources & evidence

ORD record
ord-c008ce5723f84c369529c3acd22e8d62
Source dataset
uspto-grants-1996_01
Patent number
US05482956

Reaction notes

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