HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,4-Dimethoxybenzene → HCID 18994059, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,4-Dimethoxybenzene | HCID 9016 | — |
| Reactant | Glyoxal, phenyl-, hydrate | HCID 12215922 | — |
| Catalyst | Titanium Tetrachloride | HCID 24193 | — |
| Solvent | 1,1-Dichloroethane | HCID 6365 | — |
| Product | HCID 18994059 | HCID 18994059 | — |
Reaction Steps
Phenylglyoxal monohydrate (152 mg, 1 mM) and p-dimethoxybenzene (0.21 ml, 1.5 mM) were dissolved in dichloroethane (2 ml), titanium tetrachloride (0.33 ml, 3 mM) was added, and reacted at room temperature for 4 hours. Using the same procedure as in Example 1, 2',5'-dimethoxylbenzoin was obtained as an oil (219.4 mg, 79.2% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05484689 |
| Source dataset | uspto-grants-1996_01 |
| ORD ID | ord-0df4ea03fddd4bd1be57cebf5df29192 |
| Source note | uspto-grants-1996_01 |