HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formaldehyde → 2-(Piperidinomethyl)-1-Naphthol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formaldehyde | HCID 712 | — |
| Reactant | 1-Naphthol | HCID 7005 | — |
| Reactant | Piperidine | HCID 8082 | — |
| Reactant | Morpholine | HCID 8083 | — |
| Product | 2-(Piperidinomethyl)-1-Naphthol | HCID 241241 | — |
| Product | 1-Naphthalenol, 2-(4-morpholinylmethyl)- | HCID 382950 | — |
Reaction Steps
Anon. (USA) (Res. Discl., 236, 380 (Ger), 1983) discloses a Mannich reaction of 1-naphthol with formalin and piperidine or morpholine to yield 2-(piperidinomethyl)-1-naphthol or 2-(morpholinomethyl)-1-naphthol, respectively. These compounds were subjected to hydrogenolysis (Pd/C) whereby 2-methyl-1-naphthol was produced
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05420362 |
| Source dataset | uspto-grants-1995_05 |
| ORD ID | ord-845bb11cfab64d898e0390f7ee4a116c |
| Source note | uspto-grants-1995_05 |