3,5-Dinitrobenzyl alcohol → (3,5-Diaminophenyl)methanol

HRID 383005Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 383005
[N+:1]([C:4]1[CH:5]=[C:6]([CH:9]=[C:10]([N+:12]([O-])=O)[CH:11]=1)[CH2:7][OH:8])([O-])=O>CO.[Pd]>[NH2:1][C:4]1[CH:5]=[C:6]([CH:9]=[C:10]([NH2:12])[CH:11]=1)[CH2:7][OH:8]

Komponenten

4

Edukt 1

HCID 1169783,5-Dinitrobenzyl alcohol

Produkt 1

HCID 586680(3,5-Diaminophenyl)methanol

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23938PalladiumKatalysatorHCID 887MethanolLösungsmittel

Versuchsvorschrift

A solution of 3,5-dinitrobenzylalcohol (2.20 g, 11.1 mmol) in methanol (90 ml) and a Pd/C catalyst (10%, 100 mg) was hydrogenated in a Parr apparatus at 60 psi. The solution was filtered and the solvent was removed by evaporation. The crude product was used without purification in the next step.

Aufarbeitung

  1. filtrationThe solution was filtered
  2. customthe solvent was removed by evaporation
  3. customThe crude product was used without purification in the next step

Quellen und Nachweise

ORD-Eintrag
ord-6f3794a4110d43eeab4b96c5350d1f6c
Quelldatensatz
uspto-grants-2001_10
Patentnummer
US06310243B1

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