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HRID383049

反应详情

EQUATION

反应方程式

HRID 383049 的结构方程式

REACTANTS

反应物

2
反应SMILES：CC1(C)OCC(C(=O)Cl)O1
HCID13974813

未命名化合物

反应SMILES：CC(=O)OCCc1c(I)c(N)c(I)c(N)c1I
HCID18429166

未命名化合物

PRODUCTS

产物

1
反应SMILES：CC(=O)OCCc1c(I)c(NC(=O)C2COC(C)(C)O2)c(I)c(NC(=O)C2COC(C)(C)O2)c1I
HCID86754866

未命名化合物

收率 47%

PROCEDURE

实验过程

3,5-Diamino-2,4,6-triiodo-(2-acetoxyethyl)benzene was acylated with 2,2-dimethyl-1,3-dioxolane-4-carboxylic chloride (prepared in situ) according to the procedure in Example 29a. After work up, the product was purified by preparative HPLC and isolated in 47% yield.

WORKUP

后处理

  1. customAfter work up, the product was purified by preparative HPLC
  2. customisolated in 47% yield