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HRID387401

反应详情

EQUATION

反应方程式

HRID 387401 的结构方程式

REACTANTS

反应物

2
结构：C#Cc1ccccc1
HCID10821

Phenylacetylene

C8H6

结构：[N-]=[N+]=NCc1ccccc1
HCID12152

Benzyl azide

C7H7N3

PRODUCTS

生成物

1
结构：c1ccc(Cn2nncc2-c2ccccc2)cc1
HCID12247343

1-benzyl-5-phenyl-1H-1,2,3-triazole

C15H13N3

AUXILIARIES

试剂、催化剂与溶剂

2
结构：Cc1c(C)c(C)[c-](C)c1C.[Cl][Ru+].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1
催化剂HCID71310463

Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2)

C46H45ClP2Ru

结构：c1ccccc1
溶剂HCID241

Benzene

C6H6

PROCEDURE

实验过程

Benzyl azide (0.100 g, 0.751 mmol), phenylacetylene (0.150 mL, 1.37 mmol), Cp*RuCl(PPh3)2 (30 mg, 0.038 mmol). Solvent, benzene; reaction temperature, r.t.; reaction time, 24 hours; yield, 0.13 g (75%). EI-MS: m/z 236 [M+1].

WORKUP

后处理

  1. customreaction temperature, r.t.
  2. customreaction time, 24 hours
  3. customyield