HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenylacetylene → 1-benzyl-5-phenyl-1H-1,2,3-triazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenylacetylene | HCID 10821 | — |
| Reactant | Benzyl azide | HCID 12152 | — |
| Catalyst | Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2) | HCID 71310463 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 1-benzyl-5-phenyl-1H-1,2,3-triazole | HCID 12247343 | — |
Reaction Steps
Benzyl azide (0.100 g, 0.751 mmol), phenylacetylene (0.150 mL, 1.37 mmol), Cp*RuCl(PPh3)2 (30 mg, 0.038 mmol). Solvent, benzene; reaction temperature, r.t.; reaction time, 24 hours; yield, 0.13 g (75%). EI-MS: m/z 236 [M+1].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08372986B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-bcb97887a4644bcea677ea7136756d07 |
| Source note | uspto-grants-2013_02 |