Benzyl azide → HCID 16129277, compound

HRID 387403Notes

Reaction equation

HRID 387403 reaction equation
[CH2:1]([N:8]=[N+:9]=[N-:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH:11]#[C:12][CH2:13][CH2:14][CH2:15][CH3:16]>C[C-]1C(C)=C(C)C(C)=C1C.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.Cl[Ru+].C1C=CC=CC=1>[CH2:1]([N:8]1[C:12]([CH2:13][CH2:14][CH2:15][CH3:16])=[CH:11][N:10]=[N:9]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 2

HCID 12152Benzyl azideHCID 127321-Hexyne

Product 1

HCID 16129277HCID 16129277, compound

Reagents, catalysts & solvents 2

HCID 71310463Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2)CatalystHCID 241BenzeneSolvent

Procedure

Benzyl azide (0.340 g, 2.55 mmol), 1-hexyne (0.580 ml, 5.05 mmol), Cp*RuCl(PPh3)2 (50 mg, 0.063 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 3 hours; yield, 0.45 g (82%). EI-MS: m/z 216 [M+1].

Workup

  1. customreaction temperature, 80° C.
  2. customreaction time, 3 hours
  3. customyield

Sources & evidence

ORD record
ord-0a14131248a44ec1bfdc8fbaf681e904
Source dataset
uspto-grants-2013_02
Patent number
US08372986B2

Reaction notes

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