HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl azide → HCID 16129277, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl azide | HCID 12152 | — |
| Reactant | 1-Hexyne | HCID 12732 | — |
| Catalyst | Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2) | HCID 71310463 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | HCID 16129277 | HCID 16129277 | — |
Reaction Steps
Benzyl azide (0.340 g, 2.55 mmol), 1-hexyne (0.580 ml, 5.05 mmol), Cp*RuCl(PPh3)2 (50 mg, 0.063 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 3 hours; yield, 0.45 g (82%). EI-MS: m/z 216 [M+1].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08372986B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-0a14131248a44ec1bfdc8fbaf681e904 |
| Source note | uspto-grants-2013_02 |