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HRID387406

反应详情

EQUATION

反应方程式

HRID 387406 的结构方程式

REACTANTS

反应物

2
结构：C#CC(C)(C)O
HCID8258

2-Methyl-3-butyn-2-ol

C5H8O

结构：[N-]=[N+]=NCc1ccccc1
HCID12152

Benzyl azide

C7H7N3

PRODUCTS

生成物

1
结构：CC(C)(O)c1cnnn1Cc1ccccc1
HCID11687175

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：Cc1c(C)c(C)[c-](C)c1C.[Cl][Ru+].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1
催化剂HCID71310463

Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2)

C46H45ClP2Ru

结构：c1ccccc1
溶剂HCID241

Benzene

C6H6

PROCEDURE

实验过程

Benzyl azide (0.400 g, 3.00 mmol), 2-methyl-3-butyn-2-ol (0.290 ml, 3.00 mmol), Cp*RuCl(PPh3)2 (25 mg, 0.031 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 2.5 hours; yield, 0.63 g (96%). EI-MS: m/z 218 [M+1 ].

WORKUP

后处理

  1. customreaction temperature, 80° C.
  2. customreaction time, 2.5 hours
  3. customyield