HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methyl-3-butyn-2-ol → HCID 11687175, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methyl-3-butyn-2-ol | HCID 8258 | — |
| Reactant | Benzyl azide | HCID 12152 | — |
| Catalyst | Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2) | HCID 71310463 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | HCID 11687175 | HCID 11687175 | — |
Reaction Steps
Benzyl azide (0.400 g, 3.00 mmol), 2-methyl-3-butyn-2-ol (0.290 ml, 3.00 mmol), Cp*RuCl(PPh3)2 (25 mg, 0.031 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 2.5 hours; yield, 0.63 g (96%). EI-MS: m/z 218 [M+1 ].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08372986B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-9fe90d8b14dd484cad1eca052c711e6c |
| Source note | uspto-grants-2013_02 |