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HRID387412

反应详情

EQUATION

反应方程式

HRID 387412 的结构方程式

REACTANTS

反应物

2
反应SMILES：C(#Cc1ccccc1)c1ccccc1
HCID10390

Benzene, 1,1'-(1,2-ethynediyl)bis-

C14H10

反应SMILES：[N-]=[N+]=NCc1ccccc1
HCID12152

Benzyl azide

C7H7N3

PRODUCTS

产物

1
反应SMILES：c1ccc(Cn2nnc(-c3ccccc3)c2-c2ccccc2)cc1
HCID283388

1H-1,2,3-Triazole, 1-benzyl-4,5-diphenyl-

C21H17N3

AUXILIARIES

试剂、催化剂与溶剂

2
反应SMILES：Cc1c(C)c(C)[c-](C)c1C.[Cl][Ru+].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1
催化剂HCID71310463

Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2)

C46H45ClP2Ru

反应SMILES：c1ccccc1
溶剂HCID241

Benzene

C6H6

PROCEDURE

实验过程

Benzyl azide (0.400 g, 3.00 mmol), diphenylacetylene (0.588 g, 3.30 mmol), Cp*RuCl(PPh3)2 (25 mg, 0.031 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 2 hours; yield, 0.75 g (80%). EI-MS: m/z 312 [M+1].

WORKUP

后处理

  1. customreaction temperature, 80° C.
  2. customreaction time, 2 hours
  3. customyield