HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diphenylacetylene → 1H-1,2,3-Triazole, 1-benzyl-4,5-diphenyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diphenylacetylene | HCID 10390 | — |
| Reactant | Benzyl azide | HCID 12152 | — |
| Catalyst | Chlororuthenium(1+) 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-ide--triphenylphosphane (1/1/2) | HCID 71310463 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 1H-1,2,3-Triazole, 1-benzyl-4,5-diphenyl- | HCID 283388 | — |
Reaction Steps
Benzyl azide (0.400 g, 3.00 mmol), diphenylacetylene (0.588 g, 3.30 mmol), Cp*RuCl(PPh3)2 (25 mg, 0.031 mmol). Solvent, benzene; reaction temperature, 80° C.; reaction time, 2 hours; yield, 0.75 g (80%). EI-MS: m/z 312 [M+1].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08372986B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-552e1eb460184a13962895d2a98a30b6 |
| Source note | uspto-grants-2013_02 |