HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl mercaptan → 1-Benzylsulfanyl-3-bromo-2-trifluoromethyl-benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl mercaptan | HCID 7509 | — |
| Reactant | 2-Bromo-6-fluorobenzotrifluoride | HCID 2773345 | — |
| Product | 1-Benzylsulfanyl-3-bromo-2-trifluoromethyl-benzene | HCID 67155259 | — |
Reaction Steps
Phenyl-methanethiol (4.g g, 37.0 mmol) was treated with commercially available 1-bromo-3-fluoro-2-trifluoromethyl-benzene (10.0 g, 41.1 mmol) in close analogy to the procedure described in step 5.3). The crude product (10.5 g) after workup was used as such in the next reaction step without purification by chromatography.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08378092B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-e82cb9c16d524ad382d59b2d011bdb18 |
| Source note | uspto-grants-2013_02 |