HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Anhydride → HCID 86759544, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Reactant | 2,4-Hexanedione, 1,1,1-trifluoro-5-methyl- | HCID 160191 | — |
| Reactant | Ethylorthoformate | HCID 53630039 | — |
| Product | HCID 86759544 | HCID 86759544 | 67% |
Reaction Steps
A mixture comprising 213 g (1.17 mol) of 1,1,1-trifluoro-5-methyl-2,4-hexanedione, 242 g (1.64 mol) of ethyl orthoformate and 166 g (1.63 mol) of acetic anhydride, was heated and refluxed for 6 hours. The solvent was distilled off under reduced pressure to obtain 146 g (yield: 67%) of 3-ethoxymethylene-1,1,1-trifluoro-5-methyl-2,4-hexanedione.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06806230B1 |
| Source dataset | uspto-grants-2004_10 |
| ORD ID | ord-c6489a92ee5f47b3a4043b0ee3b2fd42 |
| Source note | uspto-grants-2004_10 |