Pentane → HCID 131720369, compound

HRID 393303Notes

Reaction equation

HRID 393303 reaction equation
[CH3:1][C:2]1[C:3]([CH3:21])=[C:4]([CH3:20])[C:5]([Si:8]([NH:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[O:18][CH3:19])([CH3:10])[CH3:9])([CH3:7])[CH:6]=1.C([Li:26])CCC.CCCCC>C(OCC)C.CCCCCC>[CH3:1][C:2]1[C:3]([CH3:21])=[C:4]([CH3:20])[C:5]([Si:8]([N-:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[O:18][CH3:19])([CH3:10])[CH3:9])([CH3:7])[CH:6]=1.[Li+:26].[Li+:26].[CH3:1][C:2]1[C:3]([CH3:21])=[C:4]([CH3:20])[C:5]([Si:8]([N-:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[O:18][CH3:19])([CH3:10])[CH3:9])([CH3:7])[CH:6]=1

Participants

6

Reactant 3

HCID 8003PentaneHCID 131720370HCID 131720370, compoundHCID 178418339Butyllithium

Product 1

HCID 131720369HCID 131720369, compound

Reagents, catalysts & solvents 2

HCID 3283Diethyl EtherSolventHCID 8058HexaneSolvent

Procedure

To 1.4 g (4.6 mmol) ((tetramethylcyclopentadienyl)dimethylsilyl)(2-methoxyphenyl)amine in diethyl ether was added dropwise 3.9 mL of 2.5 M butyl lithium (9.8 mmol) in hexane solvent. A white precipitate formed. Pentane was added to the mixture. The slurry was filtered and the solids washed with pentane.

Workup

  1. customA white precipitate formed
  2. filtrationThe slurry was filtered
  3. washthe solids washed with pentane

Sources & evidence

ORD record
ord-44f43ec93ec141b590c64e5ceee0c442
Source dataset
uspto-grants-2004_10
Patent number
US06806326B2

Reaction notes

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