Sodium Azide → HCID 178514548, compound

HRID 398345Notes

Reaction equation

HRID 398345 reaction equation
Cl[CH2:2][C:3]1[CH:11]=[CH:10][C:6]2[NH:7][N:8]=[N:9][C:5]=2[CH:4]=1.[N-:12]=[N+:13]=[N-:14].[Na+]>CN(C=O)C>[N:12]([CH2:2][C:3]1[CH:11]=[CH:10][C:6]2[NH:7][N:8]=[N:9][C:5]=2[CH:4]=1)=[N+:13]=[N-:14]

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 178478430HCID 178478430, compound

Product 1

HCID 178514548HCID 178514548, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

To a solution of 5-chloromethyl-1,2,3-benzotriazole (2.2 g, 12.2 mmol, Katritzky et al. Synth. Commun. 1993, 23, 2019) dissolved in DMF (25 mL) was added sodium azide (2.4 g, 36.5 mmol). The resulting mixture was stirred under Ar for 16 h and the precipitated product was filtered and air dried to afford the title compound:

Workup

  1. filtrationthe precipitated product was filtered
  2. customair dried

Sources & evidence

ORD record
ord-2e6b5afb51034aaeaa23e2a28fc1976d
Source dataset
uspto-grants-2003_08
Patent number
US06610692B1

Reaction notes

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