HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dichloromethane → HCID 18969717, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | 4,4-Dichloro-3-(4-methylthiophenyl)-2-phenyl-2-cyclobuten-1-one | HCID 17881582 | — |
| Reactant | Potassium hydroxy sulfite | HCID 23707502 | — |
| Solvent | Methanol | HCID 887 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | HCID 18969717 | HCID 18969717 | — |
Reaction Steps
To a solution of Example 1 (790mg) in CH2Cl2 (10 mL) and MeOH (10 mL) was added a solution of Oxone® (3.6 g) in H2O (10 mL). The mixture was stirred at r.t. for 2 hr and diluted with Et2O. The organic phase was washed with H2O, brine, dried (MgSO4) and the solvents evaporated. The resulting solid residue was stirred vigorously in hexane/Et2O for 1 hr and then filtered to afford the title compound as a yellow solid, m.p. 124°-125° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05817700 |
| Source dataset | uspto-grants-1998_10 |
| ORD ID | ord-c91f3ae9e5804549afb4cc2631bbc5a8 |
| Source note | uspto-grants-1998_10 |