Stannous Chloride → HCID 85766638, compound

HRID 399289Notes

Reaction equation

HRID 399289 reaction equation
[Sn:1]([Cl:3])[Cl:2].[C:4]([CH2:7][C:8](=[O:10])[CH3:9])(=O)[CH3:5].C([Cl:21])(=O)C=CC1C=CC=CC=1>C(OCC)C>[CH3:5][C:4]([Sn:1]([Cl:21])([Cl:3])[Cl:2])=[CH:7][C:8](=[O:10])[CH3:9]

Participants

5

Reactant 3

HCID 24479Stannous ChlorideHCID 31261AcetylacetoneHCID 660233-Phenylprop-2-enoyl chloride

Product 1

HCID 85766638HCID 85766638, compoundYield 101.6%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

The procedure was analogous to Example 6. 50 g (0.26 mol) of tin(II) chloride and 25.6 g (0.26 mol) of acetylacetone was reacted with 44 g (0.26 mol) of cinnamoyl chloride in 150 ml of diethyl ether to give a quantitative yield of 81.4 g of 1-methylbut-1-en-3-onyltin trichloride.

Sources & evidence

ORD record
ord-632b97e2168f4eac891e25124716dada
Source dataset
uspto-grants-1998_10
Patent number
US05817851

Reaction notes

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