HCID 15347493, compound → HCID 15347494, compound

HRID 400246Notes

Reaction equation

HRID 400246 reaction equation
CC(C)=[O:3].OS(O)(=O)=O.O=[Cr](=O)=O.[CH:14]([N:17]([CH:36]([CH3:38])[CH3:37])[C:18](=[O:35])[CH2:19][O:20][C:21]1[CH:26]=[CH:25][C:24]([C:27]2[CH:32]=[CH:31][C:30]([CH:33]=[O:34])=[CH:29][CH:28]=2)=[CH:23][CH:22]=1)([CH3:16])[CH3:15]>CC(C)=O>[CH:36]([N:17]([CH:14]([CH3:16])[CH3:15])[C:18](=[O:35])[CH2:19][O:20][C:21]1[CH:26]=[CH:25][C:24]([C:27]2[CH:28]=[CH:29][C:30]([C:33]([OH:3])=[O:34])=[CH:31][CH:32]=2)=[CH:23][CH:22]=1)([CH3:38])[CH3:37]

Participants

4

Reactant 2

HCID 15347493HCID 15347493, compoundHCID 131709961Jones' reagent

Product 1

HCID 15347494HCID 15347494, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

0.85 ml of Jones' reagent were introduced under an inert gas atmosphere into a solution of 741 mg of the product of stage B in 10 ml of acetone and the mixture was stirred for 7 hours. The precipitate formed was filtered off and dried to obtain 620 mg of the expected product with a Rf=0.5 (dichloromethane/methanol 9/1).

Workup

  1. customThe precipitate formed
  2. filtrationwas filtered off
  3. customdried

Sources & evidence

ORD record
ord-f3121baa3b404381ae671b1c142c075c
Source dataset
uspto-grants-1998_10
Patent number
US05827887

Reaction notes

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