HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 408575Generated: October 29, 2026
Benzo[d]thiazol-5-ylmethanol → 1,3-Benzothiazole-5-carbaldehyde
https://huagongshe.com/reaction/408575
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Benzo[d]thiazol-5-ylmethanol | HCID 22281733 | — |
| Catalyst | Manganese dioxide | HCID 14801 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 1,3-Benzothiazole-5-carbaldehyde | HCID 21873718 | — |
Reaction Steps
To a solution of benzothiazol-5-yl-methanol (1 eq.) in DCM was added MnO2 (10 eq.). The dark suspension was stirred at 20° C. for 15 h, filtered through a pad of celite and the solvent removed under reduced pressure to afford benzothiazole-5-carbaldehyde which was used as such without further purification.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US08759334B2 |
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| Source dataset | uspto-grants-2014_06 |
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| ORD ID | ord-369831751b674dc4b9a51dbd8cf70f4a |
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| Source note | uspto-grants-2014_06 |
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