1,3-Cyclohexadiene → HCID 22880219, compound

HRID 413066Notes

Reaction equation

HRID 413066 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:25]=[CH:26][C:27]=1[O:28][CH3:29])[CH2:6][N:7]1[C:13](=[O:14])[C@@H:12]2[C@H:8]1[CH2:9][CH2:10][N:11]2C(OCC1C=CC=CC=1)=O.C1CCC=CC=1>[Pd]>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:25]=[CH:26][C:27]=1[O:28][CH3:29])[CH2:6][N:7]1[C:13](=[O:14])[C@@H:12]2[C@H:8]1[CH2:9][CH2:10][NH:11]2

Participants

4

Reactant 2

HCID 116051,3-CyclohexadieneHCID 86751735HCID 86751735, compound

Product 1

HCID 22880219HCID 22880219, compound

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

This compound was prepared analogously to Example 2 from benzyl (1S,5R)-6-(3,4-dimethoxybenzyl)-7-oxo-2,6-diazabicyclo[3.2.0]heptane-2-carboxylate by treatment with Pd/C and cyclohexadiene.

Sources & evidence

ORD record
ord-5daeb85bcbb14bb6850f787877aa6a38
Source dataset
uspto-grants-2003_05
Patent number
US06566355B1

Reaction notes

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