1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoroheptan-1-OL → Octafluoro-1-pentanol

HRID 413614Notes

Reaction equation

HRID 413614 reaction equation
FC(F)(C)[C:3](F)(F)[C:4]([F:16])([F:15])[C:5]([F:14])([F:13])[C:6]([F:12])([F:11])[C:7]([F:10])([F:9])[OH:8]>FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F>[F:15][C:4]([F:16])([CH3:3])[C:5]([F:13])([F:14])[C:6]([F:11])([F:12])[C:7]([F:10])([F:9])[OH:8]

Participants

3

Reactant 1

HCID 222779521,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoroheptan-1-OL

Product 1

HCID 216319Octafluoro-1-pentanol

Reagents, catalysts & solvents 1

HCID 12675PerfluoropentaneSolvent2×

Procedure

A 1.0 mL portion of dodecafluoroheptanol (PCR) was added to 1.0 mL of dodecafluoropentane to form a clear, homogenous solution. The same quantity of octafluoropentanol in dodecafluoropentane yielded two clear, non-mixing phases. The addition of 2.0 to 4.0 mL water to the dodecafluoroheptanol-dodecafluoropentane yielded two non-mixing phases. Upon cooling to 4° C. the two clear phases changed to three clear phases.

Workup

  1. customto form a clear, homogenous solution

Sources & evidence

ORD record
ord-d361fceb868746c3823ffc4dce892d3d
Source dataset
uspto-grants-2003_05
Patent number
US06569404B1

Reaction notes

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