3-Chlorobenzoic Acid → HCID 14347925, compound

HRID 414008Notes

Reaction equation

HRID 414008 reaction equation
[F:1][CH:2]([F:21])[C:3]1[N:8]=[C:7]([C:9]([F:12])([F:11])[F:10])[C:6]([C:13]([O:15][CH2:16][CH3:17])=[O:14])=[C:5]([CH3:18])[C:4]=1[S:19][CH3:20].C1C=C(Cl)C=C(C(OO)=[O:30])C=1.C1C=C(Cl)C=C(C(O)=O)C=1>>[F:21][CH:2]([F:1])[C:3]1[N:8]=[C:7]([C:9]([F:12])([F:10])[F:11])[C:6]([C:13]([O:15][CH2:16][CH3:17])=[O:14])=[C:5]([CH3:18])[C:4]=1[S:19]([CH3:20])=[O:30]

Participants

4

Reactant 3

HCID 4473-Chlorobenzoic AcidHCID 70297m-Chloroperbenzoic acidHCID 14347924HCID 14347924, compound

Product 1

HCID 14347925HCID 14347925, compound

Procedure

Prepared from product of Example 1 (5.75 g, 17.5 mmol) and MCPBA (3.4 g of an 85% mixture with MCBA; 17.5 mmol) as described above. Recrystallization (ether) afforded the product as a white solid (5.23 g).

Workup

  1. customRecrystallization (ether)

Sources & evidence

ORD record
ord-e48a0485a85e48d1be4bd1ea61ed2f63
Source dataset
uspto-grants-1988_12
Patent number
US04789395

Reaction notes

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