3-Chlorobenzoic Acid → HCID 86742591, compound

HRID 414009Notes

Reaction equation

HRID 414009 reaction equation
[F:1][CH:2]([F:22])[C:3]1[N:8]=[C:7]([C:9]([F:12])([F:11])[F:10])[C:6]([C:13]([O:15][CH2:16][CH3:17])=[O:14])=[C:5]([CH2:18][CH3:19])[C:4]=1[S:20][CH3:21].C1C=C(Cl)C=C(C(OO)=[O:31])C=1.C1C=C(Cl)C=C(C(O)=O)C=1>>[F:22][CH:2]([F:1])[C:3]1[N:8]=[C:7]([C:9]([F:12])([F:10])[F:11])[C:6]([C:13]([O:15][CH2:16][CH3:17])=[O:14])=[C:5]([CH2:18][CH3:19])[C:4]=1[S:20]([CH3:21])=[O:31]

Participants

4

Reactant 3

HCID 4473-Chlorobenzoic AcidHCID 70297m-Chloroperbenzoic acidHCID 14347926HCID 14347926, compound

Product 1

HCID 86742591HCID 86742591, compound

Procedure

Prepared from product of Example 2 (5.8 g, 16.9 mmol) and MCPBA (3.43 g, of an 85% mixture with MCBA, 16.9 mmol) as described above. Recrystallization (ether/petroleum ether) afforded the product as a white solid (5.39 g).

Workup

  1. customRecrystallization (ether/petroleum ether)

Sources & evidence

ORD record
ord-1192942e6d844b498ce633b9f19f8c69
Source dataset
uspto-grants-1988_12
Patent number
US04789395

Reaction notes

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