3-Chlorobenzoic Acid → HCID 86742595, compound

HRID 414013Notes

Reaction equation

HRID 414013 reaction equation
[F:1][CH:2]([F:26])[C:3]1[N:8]=[C:7]([C:9]([F:12])([F:11])[F:10])[C:6]([C:13]([O:15][CH2:16][CH3:17])=[O:14])=[C:5]([CH3:18])[C:4]=1[S:19][C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1.C1C=C(Cl)C=C(C(OO)=[O:35])C=1.C1C=C(Cl)C=C(C(O)=O)C=1>>[F:26][CH:2]([F:1])[C:3]1[N:8]=[C:7]([C:9]([F:12])([F:10])[F:11])[C:6]([C:13]([O:15][CH2:16][CH3:17])=[O:14])=[C:5]([CH3:18])[C:4]=1[S:19]([C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)=[O:35]

Participants

4

Reactant 3

HCID 4473-Chlorobenzoic AcidHCID 70297m-Chloroperbenzoic acidHCID 14347931HCID 14347931, compound

Product 1

HCID 86742595HCID 86742595, compound

Procedure

Prepared from product of example 7 (6.0 g, 15.3 mmol) and MCPBA (3.11 g of an 85% mixture with MCBA, (ether/petroleum ether) afforded the product as a white solid (4.85 g).

Sources & evidence

ORD record
ord-7adc7a0d9efa442aae36332ffc95b9f5
Source dataset
uspto-grants-1988_12
Patent number
US04789395

Reaction notes

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