3-Chlorobenzoic Acid → HCID 86742598, compound

HRID 414016Notes

Reaction equation

HRID 414016 reaction equation
[F:1][CH:2]([F:24])[C:3]1[N:8]=[C:7]([C:9]([F:12])([F:11])[F:10])[C:6]([C:13]([O:15][CH2:16][CH3:17])=[O:14])=[C:5]([CH2:18][CH3:19])[C:4]=1[S:20][CH:21]([CH3:23])[CH3:22].C1C=C(Cl)C=C(C(OO)=[O:33])C=1.C1C=C(Cl)C=C(C(O)=O)C=1>>[F:24][CH:2]([F:1])[C:3]1[N:8]=[C:7]([C:9]([F:12])([F:10])[F:11])[C:6]([C:13]([O:15][CH2:16][CH3:17])=[O:14])=[C:5]([CH2:18][CH3:19])[C:4]=1[S:20]([CH:21]([CH3:22])[CH3:23])=[O:33]

Participants

4

Reactant 3

HCID 4473-Chlorobenzoic AcidHCID 70297m-Chloroperbenzoic acidHCID 14347935HCID 14347935, compound

Product 1

HCID 86742598HCID 86742598, compound

Procedure

Prepared from product of Example 11 (5.89 g, 15.86 mmol) and MCPBA (3.22 g of an 85% mixture with MCBA, 15.86 mmol) as described above. Recrystallization (ether/petroleum ether) afforded the product as a white solid (6.2 g).

Workup

  1. customRecrystallization (ether/petroleum ether)

Sources & evidence

ORD record
ord-07d0f8c40d3c47ecad9f1bbbea8c9c9a
Source dataset
uspto-grants-1988_12
Patent number
US04789395

Reaction notes

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