HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenol → o-(Methylthio)phenol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenol | HCID 996 | — |
| Reactant | 4-(Methylthio)phenol | HCID 14086 | — |
| Product | o-(Methylthio)phenol | HCID 61261 | 41% |
Reaction Steps
The mixture was cooled to room temperature and filtered. The catalyst was washed several times with ether and allowed to dry. The filtrate and ether washings were combined, and volatiles were removed on a rotary flash evaporator. GC analysis indicated the presence of phenol (5.3 g. 42% recovered), ortho(methylthio)phenol (5.2 g. 41% yield), para-(methylthio)phenol (2.0 g, and di-(methylthio)phenols (2.0 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04792633 |
| Source dataset | uspto-grants-1988_12 |
| ORD ID | ord-f0b963b8906f4ca48af00e7e02df47d0 |
| Source note | uspto-grants-1988_12 |