HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → HCID 14349152, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Phenol | HCID 996 | — |
| Reactant | Dibenzyl ether | HCID 7657 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | HCID 14349152 | HCID 14349152 | 83% |
Reaction Steps
The benzyl ether of the desired phenol (26 g) was taken in methanol (150 ml) and this solution was hydrogenated in a Parr apparatus under an atmosphere of hydrogen (45-50 lbs./sq.in.) in the presence of 10% palladium on charcoal (10 g). After 20-24 hours, the suspension was filtered on celite; all methanol was removed to obtain the desired phenol in about 83% yield (15.4 g) as a coloress liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04794188 |
| Source dataset | uspto-grants-1988_12 |
| ORD ID | ord-ea4a23cde1f74e8fbace4d17864417bf |
| Source note | uspto-grants-1988_12 |