HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Methoxycarbonyl-2-isopropylidene hydrazine → Methyl 2-isopropylhydrazinecarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Methoxycarbonyl-2-isopropylidene hydrazine | HCID 909521 | — |
| Catalyst | Adams' catalyst | HCID 345198 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | Methyl 2-isopropylhydrazinecarboxylate | HCID 57863323 | 77.6% |
Reaction Steps
N′-Isopropylidene-hydrazine-carboxylic acid methyl ester (6.45 g) were dissolved in ethanol (50 mL) and acetic acid (50 mL). PtO2 (0.231 g) was added, and reaction was stirred at room temperature for 22 hours under an atmosphere of hydrogen. Mixture was evaporated under vacuum, giving N′-Isopropyl-hydrazine-carboxylic acid methyl ester (5.08 g, 77%) as a white solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08088368B2 |
| Source dataset | uspto-grants-2012_01 |
| ORD ID | ord-3d4be84114a5432786f6919c3c67770e |
| Source note | uspto-grants-2012_01 |