反应详情

Synthesized as described above for compound 7. Quantities: resorcinol (1.79 g, 16 mmol), 11 (5.52 g, 13 mmol), NaH2PO4·H2O (6.29 g, 40 mmol), NaClO2 (7.03 g, 77 mmol). Yield 5.55 g (quant.). 1H NMR: δH (CDCl3; 300 MHz): 0.89 (3 H, t, 3J=6.9 Hz, CH3), 1.17-1.71 (18 H, m, CH2), 1.83 (2 H, m, O—CH2—CH2), 4.05 (2 H, t, 3J=6.6 Hz, O—CH2), 6.99 (2 H, d, 3J=8.9 Hz, Ar—H), 7.35 (2 H, d, 3J=8.6 Hz, Ar—H), 8.14 (2 H, d, 3J=8.9 Hz, Ar—H), 8.17 (2 H, d, 3J=8.6 Hz, Ar—H). 13C NMR: δC (CDCl3; 300 MHz): 14.1, 22.7, 26.0, 29.1, 29.3, 29.5, 29.6, 29.6, 29.7, 31.9, 68.4, 114.4, 120.9, 122.0, 126.5, 131.9, 132.4, 155.5, 170.3.

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