2-(4-Bromophenyl)-1-phenyl-1H-benzo(d)imidazole → 2-[5-(10-naphthalene-2-yl-anthracene-9-yl)-pyridine-3-yl]-1-phenyl-1H-benzimidazole

HRID 420458Notes

Reaction equation

HRID 420458 reaction equation
Br[C:2]1[CH:3]=[C:4]([C:8]2[N:12]([C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=3)[C:11]3[CH:19]=[CH:20][CH:21]=[CH:22][C:10]=3[N:9]=2)[CH:5]=[N:6][CH:7]=1.Br[C:24]1[CH:29]=[CH:28][C:27]([C:30]2N(C3C=CC=CC=3)C3C=CC=CC=3N=2)=[CH:26][CH:25]=1>>[CH:29]1[C:28]2[C:27](=[CH:30][CH:11]=[CH:10][CH:22]=2)[CH:26]=[CH:25][C:24]=1[C:26]1[C:25]2[C:24](=[CH:7][CH:2]=[CH:3][CH:4]=2)[C:29]([C:2]2[CH:3]=[C:4]([C:8]3[N:12]([C:13]4[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=4)[C:11]4[CH:19]=[CH:20][CH:21]=[CH:22][C:10]=4[N:9]=3)[CH:5]=[N:6][CH:7]=2)=[C:28]2[C:27]=1[CH:30]=[CH:14][CH:13]=[CH:18]2

Participants

3

Reactant 2

HCID 230940702-(4-Bromophenyl)-1-phenyl-1H-benzo(d)imidazoleHCID 230940852-(5-bromopyridine-3-yl)-1-phenyl-1H-benzimidazole

Product 1

HCID 866437722-[5-(10-naphthalene-2-yl-anthracene-9-yl)-pyridine-3-yl]-1-phenyl-1H-benzimidazole

Procedure

Almost the same procedure as step (2) in Synthesis Example 1 was carried out except that corresponding 2-(5-bromopyridine-3-yl)-1-phenyl-1H-benzimidazole was used instead of 2-(4-bromophenyl-phenyl-1H-benzimidazole, resultantly obtaining an aimed compound (Compound (4-6) (yield: 36%). As a result of MS analysis, it was recognized that m/e=573 for aimed substance's molecular weight of 573.22.

Workup

  1. customAlmost the same procedure as step (2) in Synthesis Example 1

Sources & evidence

ORD record
ord-8b75b90c79ba4e308c354d7609e2b5dc
Source dataset
uspto-grants-2012_01
Patent number
US08097349B2

Reaction notes

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