HCID 13460372, compound → HCID 178495624, compound

HRID 420771Notes

Reaction equation

HRID 420771 reaction equation
[CH3:1][O:2][C:3](=[O:14])[CH:4]=[C:5]1[CH2:10][CH2:9][CH:8]([CH2:11][O:12][CH3:13])[CH2:7][CH2:6]1>C(OC(=O)C)C.[Pd]>[CH3:1][O:2][C:3](=[O:14])[CH2:4][C@H:5]1[CH2:10][CH2:9][C@H:8]([CH2:11][O:12][CH3:13])[CH2:7][CH2:6]1

Participants

4

Reactant 1

HCID 13460372HCID 13460372, compound

Product 1

HCID 178495624HCID 178495624, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 8857Ethyl AcetateSolvent

Procedure

Prepared from (4-Methoxymethyl-cyclohexylidene)-acetic acid methyl ester (0.550 g, 3 mmol) by hydrogenation using Pd/C (10%) (0.295 g, 0.3 mmol) in ethylacetate (15 ml). 1/3 cis/trans mixture.

Sources & evidence

ORD record
ord-00af12539e314237b67b043274ccf09b
Source dataset
uspto-grants-2012_01
Patent number
US08097637B2

Reaction notes

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