Pyridine → 2-Propenoic acid, 2-(phenylthio)ethyl ester

HRID 420830Notes

Reaction equation

HRID 420830 reaction equation
OCC[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[SH:10].[C:11]([O-:15])(=[O:14])[CH:12]=[CH2:13].[Cl-].N1C=CC=[CH:19][CH:18]=1>>[C:11]([O:15][CH2:18][CH2:19][S:10][C:5]1[CH:4]=[CH:9][CH:8]=[CH:7][CH:6]=1)(=[O:14])[CH:12]=[CH2:13]

Participants

4

Reactant 3

HCID 1049PyridineHCID 11240608Hydroxyethyl benzene thiolHCID 21924244Chloride acrylate

Product 1

HCID 226769292-Propenoic acid, 2-(phenylthio)ethyl esterYield 80%

Procedure

60 g of hydroxyethyl benzene thiol and 44.7 g of chloride acrylate were reacted in 244 g of pyridine at 25° C. for 4 hours and then formed by distillation into 2-(phenylthio)ethyl acrylate with 80% yield. A synthetic monomer 6 was obtained with 82% yield in the same manner as in Synthesis Example 1 except that 2-(phenylthio)ethyl acrylate was used in place of phenoxyethyl acrylate.

Sources & evidence

ORD record
ord-36b75d901a2c4e6bb85a97f739ab32ee
Source dataset
uspto-grants-2012_01
Patent number
US08097688B2

Reaction notes

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