HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 67536381, compound → 6alpha-Formylandrostane-3,17-dione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 67536381 | HCID 67536381 | — |
| Reactant | 17,17-Bis(ethylendioxy)-6alpha-formylandrostane | HCID 86635567 | — |
| Product | 6alpha-Formylandrostane-3,17-dione | HCID 86635566 | 85% |
Reaction Steps
6α-Formylandrostane-3,17-dione was prepared in 85% yield from 3,3:17,17-bis(ethylendioxy)-6α-formylandrostane (Prepn. 14) by the procedure described above for the preparation of 6-methyleneandrostane-3,17-dione (II-ac, Prepn. 13). The combined organic extracts were washed with H2O, dried over Na2SO4 and evaporated to dryness to give 6α-formylandrostane-3,17-dione. 1H-NMR (300 MHz, acetone-d6, ppm from TMS): δ 9.50 (1H, d), 2.56-0.82 (21H, m), 1.16 (3H, s), 0.88 (3H, s).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08536160B2 |
| Source dataset | uspto-grants-2013_09 |
| ORD ID | ord-fb790acbf638401c9ecf22110e11c42f |
| Source note | uspto-grants-2013_09 |