huagongshe.com
HRID42128

反应详情

EQUATION

反应方程式

HRID 42128 的结构方程式

REACTANTS

反应物

2
结构：CC(C)(C)OC(=O)N1CC(C(=O)O)C1
HCID2755981

1-Boc-azetidine-3-carboxylic acid

C9H15NO4

结构：C[C@]12CC[C@H](O)CC1C(=O)C[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
HCID69012642

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)OC(=O)N1CC(C(=O)O[C@H]2CC[C@@]3(C)C(C2)C(=O)C[C@@H]2[C@@H]3CC[C@]3(C)C(=O)CC[C@@H]23)C1
HCID69009436

未命名化合物

收率 65%

PROCEDURE

实验过程

Prepared in 65% yield from 3β-hydroxyandrostane-6,17-dione and 1-(tert-butoxycarbonyl)-3-azetidinecarboxylic acid by the procedure described in Prepn. 43. 1H-NMR (300 MHz, DMSO-d6, ppm from TMS): δ 4.66 (1H, m), 4.50-1.00 (29H, m), 1.35 (9H, s), 0.78 (3H, s), 0.69 (3H, s).