HRID421532

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CN(C)c1ccc2nc3ccc(=[N+](C)C)cc-3sc2c1

HCID4139

Methylene blue cation

C16H18N3S+

HCID11105

3-Amino-7-dimethylamino-2-methylphenazine hydrochloride

C15H17ClN4

PRODUCTS

生成物

结构：CN(C)c1ccc2nc3ccc(=[N+](C)C)cc-3sc2c1.Cc1cc2nc3ccc(N(C)C)cc3nc2cc1N.Cl

HCID131729400

未命名化合物

CONDITIONS

反应条件

温度: 50 °C

PROCEDURE

实验过程

Cream-methylene blue/neutral red swatches were prepared by mixing 13.2 mg of methylene blue (Merck no. 14279) and 15.0 mg of neutral red (Merck no. 1369) with 100 g cream (38% fat, not homogenised) at 50° C., the mixture was left at this temperature for 20 minutes and filtered to remove any undissolved particles. Woven cotton swatches were immersed in the cream-methylene blue/neutral red mixture and afterwards allowed to dry at room temperature over night and frozen until use.

WORKUP

后处理

filtrationfiltered
customto remove any undissolved particles
customto dry at room temperature over night
temperaturefrozen until use

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-6cdc028ddd4c426c907ac35e00a98c85
来源数据集: uspto-grants-2012_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08101376B2
来源说明: uspto-grants-2012_01

反应 SMILES

[CH3:1][N:2]([C:4]1[CH:5]=[CH:6][C:7]2[N:20]=[C:19]3[C:11](=[CH:12][C:13]([CH:17]=[CH:18]3)=[N+:14]([CH3:16])[CH3:15])[S:10][C:8]=2[CH:9]=1)[CH3:3].[CH3:21][C:22]1[C:38]([NH2:39])=[CH:37][C:36]2[C:24](=[N:25][C:26]3[CH:31]=[CH:30][C:29]([N:32]([CH3:34])[CH3:33])=[CH:28][C:27]=3[N:35]=2)[CH:23]=1.[ClH:40]>>[CH3:3][N:2]([C:4]1[CH:5]=[CH:6][C:7]2[N:20]=[C:19]3[C:11](=[CH:12][C:13]([CH:17]=[CH:18]3)=[N+:14]([CH3:15])[CH3:16])[S:10][C:8]=2[CH:9]=1)[CH3:1].[CH3:21][C:22]1[C:38]([NH2:39])=[CH:37][C:36]2[C:24](=[N:25][C:26]3[CH:31]=[CH:30][C:29]([N:32]([CH3:34])[CH3:33])=[CH:28][C:27]=3[N:35]=2)[CH:23]=1.[ClH:40]