Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Fenteracol → 2-(2,4,5-Trichloro-phenoxy)-ethyl 2-[4-(4-chlorophenoxymethyl)-phenoxy]-propionate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Fenteracol | HCID 16462 | — |
| 반응물 | Sodium | HCID 5360545 | — |
| 반응물 | Methyl 2-[4-(4-Chlorophenoxy-methyl)-phenoxy]-propionate | HCID 19834514 | — |
| 용매 | Acetone | HCID 180 | — |
| 생성물 | 2-(2,4,5-Trichloro-phenoxy)-ethyl 2-[4-(4-chlorophenoxymethyl)-phenoxy]-propionate | HCID 53853938 | — |
반응 단계
A mixture consisting of 2.2 gm of methyl 2-[4-(4-chlorophenoxy-methyl)-phenoxy]-propionate, 2.4 gm of 2-(2,4,5-trichloro-phenoxy)-ethanol and 0.03 gm of sodium was heated at about 120°-150° C. and a pressure of 150 mm Hg for four hours. After cooling, the reaction mixture was briefly boiled with acetone, the cooled solution was filtered, and the solvent was removed from the filtrate in vacuo. The residue was recrystallized from ethanol/water, yielding 1.3 gm (36% of theory) of the compound of the formula ##STR19## which had a melting point of 83° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04169720 |
| 출처 데이터셋 | uspto-grants-1979_10 |
| ORD ID | ord-fac85202ceaa4c29acd8b6831978d813 |
| 출처 메모 | uspto-grants-1979_10 |