Sodium Iodide → 3-Methyl-6-(3,4-methylenedioxyphenyl)-3-hexenyl iodide

HRID 426869Notes

Reaction equation

HRID 426869 reaction equation
[CH3:1][C:2](=[CH:6][CH2:7][CH2:8][C:9]1[CH:14]=[CH:13][C:12]2[O:15][CH2:16][O:17][C:11]=2[CH:10]=1)[CH2:3][CH2:4]Br.[I-:18].[Na+]>CC(C)=O>[CH3:1][C:2](=[CH:6][CH2:7][CH2:8][C:9]1[CH:14]=[CH:13][C:12]2[O:15][CH2:16][O:17][C:11]=2[CH:10]=1)[CH2:3][CH2:4][I:18]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 545086813-Methyl-6-(3,4-methylenedioxyphenyl)-3-hexenyl bromide

Product 1

HCID 537947503-Methyl-6-(3,4-methylenedioxyphenyl)-3-hexenyl iodide

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

3-Methyl-6-(3,4-methylenedioxyphenyl)-3-hexenyl iodide [VI; Ar is 3,4-methylenedioxyphenyl, R is CH3 ] was prepared from 19.0 g. of 3-methyl-6-(3,4-methylenedioxyphenyl)-3-hexenyl bromide (Preparation C3) and 10.5 g. of sodium iodide in 125 ml. of acetone, to give 21 g. of product as a yellow oil.

Sources & evidence

ORD record
ord-12e521c920724b5b901a18c480084cbf
Source dataset
uspto-grants-1979_10
Patent number
US04171378

Reaction notes

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