1,2,5-Trichloro-3-nitrobenzene → 2,3,5-Trichloroaniline

HRID 429142Notes

Reaction equation

HRID 429142 reaction equation

[Cl:1][C:2]1[C:7]([Cl:8])=[CH:6][C:5]([Cl:9])=[CH:4][C:3]=1[N+:10]([O-])=O>[Fe]>[Cl:1][C:2]1[C:7]([Cl:8])=[CH:6][C:5]([Cl:9])=[CH:4][C:3]=1[NH2:10]

Participants

3

Reactant 1

HCID 64248491,2,5-Trichloro-3-nitrobenzene

Product 1

HCID 876762,3,5-TrichloroanilineYield 68%

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

2,3,5-Trichloro nitrobenzene (D12) was reduced with iron powder as described in Description 7 to give the title compound (D13) (68%), MH+ 196/198.

Sources & evidence

ORD record: ord-221a7bf9f9104774a2cfc1a34cd0c1f4
Source dataset: uspto-grants-2001_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06316450B1

Reaction notes

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