HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzaldehyde → N,N-di-n-propylbenzylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzaldehyde | HCID 240 | — |
| Reactant | Dipropylamine | HCID 8902 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | N,N-di-n-propylbenzylamine | HCID 9794124 | — |
Reaction Steps
Benzaldehyde (0.404 cm3, 4.0 mmol), di-n-propylamine (0.548 cm3, 4.0 mmol) and [Ir(COD)(dppb)][PF6] (0.070 g, 2 mol %) in dichloromethane were treated as stated above under approx 1 bar H2 at approx. 20° C. for 3 hrs. The yield of N,N-di-n-propylbenzylamine obtained was 39.6%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06323370B1 |
| Source dataset | uspto-grants-2001_11 |
| ORD ID | ord-0fdce03e711c4bd2927dfbdc8c2bc9cb |
| Source note | uspto-grants-2001_11 |